Using the cell voltage measured for the first cell studied, with cell chemistry Zn/Zn^2+ \ Cu^2+/Cu, and the known half life potential for Zn^2/Zn calculate the reduction potential for Cu^2+/Cu and enter value below.

The information received for this problem were the values obtained during an online lab:

Cu xM cell voltage:1.100 V

Range: 0.005 V

Temp: 25 degrees C

Respuesta :

Answer:

The reduction potential of   [tex]Cu^2+/Cu[/tex] is  [tex]E_c^o = 0.34 \ V[/tex]

Explanation:

From the question we are told that

      The potential of the cell is  [tex]M_{cell} = E^o _{cell} = 1.100 \ V[/tex]

       The range is  [tex]R = 0.005 \ V[/tex]

        The temperature is  [tex]T = 25 ^oC[/tex]

Note the reason why Zn is oxized and  Cu is reduced is because Zn is higher than Cu on the electrochemical series

    The reaction at the anode is  

              [tex]Zn ^{2-} _{(aq)} + 2e \to Zn_{(s)} \ \ \ \ \ E^o_a = -0.76 \ V[/tex]    

The [tex]E^o\ is \ the \ standard\ oxidation \ potential\ value\ for\ Zn\ oxidation[/tex]

    The reaction at the anode is  

             [tex]Cu^{2+} _{(aq)} + 2e^{-} \to Cu_{(s)} \ \ \ \ \ \ \ \ E^o_c = c \ V[/tex]  

Now

          [tex]E^o _{cell} = E_c^o - E_a^o[/tex]  

substituting values

           [tex]1.100 = E_c^o -(- 0.76)[/tex]

           [tex]E_c^o = 1.100 - 0.76[/tex]

           [tex]E_c^o = 0.34 \ V[/tex]

Hence the reduction potential of   [tex]Cu^2+/Cu[/tex] is  [tex]E_c^o = 0.34 \ V[/tex]